Most international driving rules apply in Kiev.  However, beware that most locals fail to follow many driving laws - Ukrainians are some of the worst speeders in the world - they love to step on the gas.  Officially, speed limits are 60 kph/37 mph in cities, 90 kph/56 mph in unpopulated areas, and 120 kph/72 mph on highways.  You can turn right on red lights, wherever there are signs.  Parking in Kiev is as difficult as in any other major European city. In downtown Kiev, many motorists park their cars on the sidewalks.

Ukraine is a Zero Tolerance country, so please do not drink and drive.  The penalties are severe and you are never sure what may happen in such incidents involving the Militia (as the local Police, is known).